审题指导:
信息①:CH3COOH、HSCN电离常数⇒酸性:HSCN>CH3COOH>H2CO3,水解能力:SCN-<CH3COO-<HCO3-<CO32-
信息②:Ka(HF)=c(F-)∙c(H+)/c(HF) ⇒pH=4时:c(F-)、c(H+)、c(HF)
(1)Ka(HSCN)>Ka(CH3COOH),溶液中c(H+):HSCN>CH3COOH,c(H+)大反应速率快 >
(2)c(F-)∙c(H+)/c(HF)=1×10-4×1.6×10-3/4×10-4=4×10-4
审题指导:
信息①:CH3COOH、HSCN电离常数⇒酸性:HSCN>CH3COOH>H2CO3,水解能力:SCN-<CH3COO-<HCO3-<CO32-
信息②:Ka(HF)=c(F-)∙c(H+)/c(HF) ⇒pH=4时:c(F-)、c(H+)、c(HF)
(1)Ka(HSCN)>Ka(CH3COOH),溶液中c(H+):HSCN>CH3COOH,c(H+)大反应速率快 >
(2)c(F-)∙c(H+)/c(HF)=1×10-4×1.6×10-3/4×10-4=4×10-4
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